SPSS is the name of a statistics software package. significance level 0.05 means you can be 95% confident (should be at least 95%) that the difference is statistically significant, i.e. the difference is not caused by chance.
Here is an example. In the Chinese Learner English Corpus (CLEC), which contains 1,070,602 words, there are 9,711 instances of passives; in the Louvain Corpus of Native English Essays (LOCNESS), which contains 324,304 words, there are 5,465 instances of passives. Is the difference statistically significant? If you compute the log-likelihood score, it will be 1235.6 (for 1 degree of freedom - if you are using UCREL LL calculator, the d.f. is 1), much greater than 3.84, or even 10.83 for significance at p<0.001. So now you are over 99.99% confident the difference is highly significant statistically. If you bring the raw frequencies of passive in the two corpora to occurrences per 100,000 words, you will find that there are about 907 instances of passive in CLEC but 1,685 instances in LOCNESS. So you can say that passives considerably under-used by Chinese learners of English.